Tungsten H₂O₂(30%)+NH₃(25%)

Chemical Etching Formula
W1 Pure Tungsten with H₂O₂(30%)+NH₃(25%)

This page documents the reference wet chemical etching formula for W1 Pure Tungsten using the H₂O₂(30%)+NH₃(25%) system. The recipe below covers a sheet-thickness range of 0.05-0.3 mm and is configured for through etch (double-sided). Every value is drawn from operational process records rather than theoretical calculation, and is provided as a starting point for your own process development.

Formula Summary

The table below summarizes every parameter that defines this etching formula. Values listed as ranges scale with sheet thickness across the supported band.

H₂O₂(30%)+NH₃(25%) Etchant System
°Bé Concentration
1.120 Specific Gravity
58 °C Bath Temperature
Through etch (double-sided) Etch Depth Type
0.05-0.3 mm Thickness Range
0.15 mm Typical Thickness
0.12-0.98 m/min Conveyor Speed Range
0.20 m/min Typical Speed
60-360 μm Min Hole Ø Range
100-300 μm Min Line Width Range
11-65 μm Undercut Range
2.30 Etch Factor (EF)
93.1% Typical Yield (92.8-93.4%)

Why H₂O₂(30%)+NH₃(25%) for W1 Pure Tungsten?

For W1 Pure Tungsten, H₂O₂(30%)+NH₃(25%) provides controllable, regenerable etching with predictable undercut. The chloride or acid species continuously break down the alloy's protective oxide while the oxidizer supplies the electrochemical driving force, producing clean, burr-free edges compatible with standard dry-film and liquid photoresists.

Process Window & Bath Control

Hold the bath at 58°C with concentration as specified (specific gravity 1.120). Across the 0.05-0.3 mm thickness range, conveyor speed runs from 0.12-0.98 m/min — thinner sheets move faster, thicker sheets slower, in roughly inverse proportion to thickness. A typical mid-range setpoint is 0.20 m/min for 0.15 mm stock. Use redundant PID temperature control to hold the bath within ±1.5°C, and titrate at least once per shift.

Design Rules & Tolerances

Design rules for this recipe: hole diameter 60-360 μm, line width 100-300 μm, single-side undercut 11-65 μm — all as a function of thickness across 0.05-0.3 mm. The higher the etch factor (this formula holds about 2.30), the tighter the achievable tolerance. Below the minimum feature sizes, yield falls off steeply, so treat those numbers as hard floors rather than targets.

Design Rule Summary
• Minimum hole diameter range: 60-360 μm
• Minimum line width range: 100-300 μm
• Single-side undercut range: 11-65 μm
• Typical etch factor (EF): 2.30

Yield & Production Economics

Typical mass-production yield for W1 Pure Tungsten in the H₂O₂(30%)+NH₃(25%) system is 93.1%, within an observed range of 92.8-93.4%. The dominant yield-loss modes are photoresist pinhole defects and rinse-water contamination. Improving incoming sheet quality and photoresist coating consistency gives the highest yield-improvement leverage for this formula.

Typical Applications

Typical applications for W1 Pure Tungsten processed with H₂O₂(30%)+NH₃(25%) include X-ray collimator grids, electron-beam apertures, and high-density precision masks. The formula's tolerance band and yield make it well suited to medium-to-high-volume precision flat parts.

More Tungsten Formulas

Other formulas in the same material family.

Frequently Asked Questions

This formula is documented for a sheet-thickness range of 0.05-0.3 mm, with a typical value of 0.15 mm. Outside this band the same chemistry may still work, but conveyor speed and feature tolerances should be re-verified with a sample run before production.

Need a Quote for This Process?

WET Etched runs production wet chemical etching lines using the H₂O₂(30%)+NH₃(25%) chemistry. Send us your part drawing and quantity for a full process quote.